Is RILES a Wordle Word?

Yes. RILES is a valid Wordle word.

It is not on the Wordle answer list, so it is unlikely to be a daily answer.

Plurals ending in S are almost never chosen as Wordle answers.

What does RILES mean?

To make angry
To stir or move from a state of calm or order“It riles me that she never closes the door after she leaves.”

Definition from Wiktionary, available under the CC BY-SA license.

Starter word rating: ExcellentIn the top 2% of all valid Wordle words for testing common letters.
Vowels: I, E
Unique letters: 5 of 5
Common letters: R, I, L, E

Hard-mode trap: 10 valid words fit the pattern RI_ES. If you reach it, you may need several guesses to find the last letter.

Letter ratings use how often each letter appears in Wordle answers.

Tap its tiles to the colours Wordle showed, and the Wordle Solver lists every word that still fits, with the best next guess.